Double-pulse laser induced breakdown spectroscopy (LIBS) measurements in water with up to 600 bar and 400 mJ each pulse were done to select laser parameters which promote optimized spectral line emission from plasma even at elevated pressures, where line broadening until loss of the most spectral information can occur. Optical emission spectroscopy, using a Czerny-Turner spectrometer, has been applied to investigate the dependence of the emitted radiation on laser parameters and hydrostatic pressure. It has been found, that higher laser pulse energies, especially with high water pressure, can also have an adverse effect on the measured spectrum. The spectral data was measured with an Roper Acton Spectra Pro 500i with connected PI-MAX2 camera. All data is available in internal spe format and as converted tif files. A metdata file with all relevant parameters is provided in xml format.

An appropriate coupling of an arc plasma column in the state of local thermodynamic equilibrium to a refractory cathode necessarily involves the non-equilibrium boundary layer between them. A model has been developed that combines a model of an equilibrium direct current arc plasma in atmospheric pressure argon with the assembly of a cathode made of tungsten and the boundary layer. A bidirectional coupling has been realized that allows us to consider a variable voltage drop across the boundary layer for different positions on the cathode. Results are obtained for arc currents between 10 and 150A in the cases of both a unidirectional and a bidirectional coupling. The results Show differences in the distributions of the temperature and the normal current density on the cathode surface, and the radial and axial distribution of the plasma temperature. Comparison with results of a fully non-equilibrium model of the arc plasma and experimental findings from optical emission spectroscopy show a fair agreement for currents, where the deviations from equilibrium in the arc column can be ignored. For arc currents beyond 100 A, the arc attachment on the cathode appears in two forms, which differ from each other in the distributions of the temperature and the normal current density on the cathode surface, whereas the values of the total arc voltage are close to each other.