In-process thermal melt pool images and post-fabrication porosity labels are acquired for Ti-6Al-4V thin-walled structure fabricated with OPTOMEC Laser Engineered Net Shaping (LENS™) 750 system. The data is collected for nondestructive thermal characterization of direct laser deposition (DLD) build. More specifically, a Stratonics Dual-wavelength pyrometer captures a top-down view of the melt pool of the deposition heat-affected zone (HAZ), which is above 1660°C, and Nikon X-Ray Computed Tomography (XCT) XT H225 captures internal porosity reflective of lack of fusion during the fabrication process. The pyrometer images provided in Comma Separated Values (CSV) format are cropped to center the melt pool to temperatures above 1000℃, indicative of the shape and distribution of temperature values. Melt pool coordinates are determined using pyrometer specifications and thin wall build parameters. XCT porosity labels of sizes between 0.05 mm to 1.00 mm are registered within 0.5 mm of the melt pool image coordinate. An XCT porosity-labeled table provided in the Excel spreadsheet format contains time stamps, melt pool coordinates, melt pool eccentricity, peak temperature, peak temperature coordinates, pore size, and pore label. Thermal-porosity data utilization aids in generating data-driven quality control models for manufacturing parts with lower degrees of porosity.