Automated Author Profile

Hanikel, Nikita

University of California, Berkeley

Current S-Index

2.3

Sum of Dataset Indices for all datasets

Average Dataset Index per Dataset

2.3

Average Dataset Index per dataset

Total Datasets

1

Total datasets for this author

Average FAIR Score

80.8%

Average FAIR Score per dataset

Total Citations

1

Total citations to the author's datasets

Total Mentions

0

Total mentions of the author's datasets

S-Index Interpretation

S-Index Over Time

Cumulative Citations Over Time

Cumulative Mentions Over Time

Datasets

Solid-state nuclear magnetic resonance data from: Covalent organic frameworks for carbon dioxide capture from air (Version: 3)

We report the first covalent incorporation of reactive aliphatic amine species into covalent organic frameworks (COFs). This was achieved through the crystallization of an imine-linked COF, termed COF-609-Im, followed by conversion of its imine linkage to base-stable tetrahydroquinoline linkage through aza-Diels-Alder cycloaddition, and finally, the covalent incorporation of tris(3-aminopropyl)amine into the framework. The obtained COF-609 exhibits a 1360-fold increase in CO2 uptake capacity compared to the pristine framework and a further 29% enhancement in the presence of humidity. We confirmed the chemistry of framework conversion and corroborated the enhanced CO2 uptake phenomenon with and without humidity through isotope-labeled Fourier transform infrared spectroscopy and solid-state nuclear magnetic resonance spectroscopy. With this study, we established a new synthetic strategy to access a class of chemisorbents characterized by high affinity to CO2 in dilute sources, such as the air.

Authors

  • Lyu, Hao ;
  • Li, Haozhe ;
  • Hanikel, Nikita ;
  • Wang, Kaiyu ;
  • Yaghi, Omar
1 Citation0 Mentions81% FAIR2.3 Dataset Index
10.6078/d1f412February 2023