The PL spectra were measured by a confocal system (WITec alpha 300R) equipped with a 405 nm continuous wave laser. Perovskite films were characterized by XRD (Philips, X pert pro MRD, with Cu Kα radiation, λ = 1.54 Å). The SEM images were observed by SEM (ZEISS Gemini SEM 300 field-emission SEM, with Pt coating). The morphology of the perovskite films was characterized by AFM (Cypher ES SPM) in the AC mode. The GIWAXS experiments were carried out at the BL17B1 beamline of Shanghai Synchrotron Radiation Facility (SSRF) using an X-ray energy of 10 keV. For the polarization-resolved ASE experiments, a 500 nm pulse as the excitation beam was focused on the samples through a cylindrical lens, and the stripe length of the spot size was controlled by using an adjustable slit. A quarter-wave plate (Thorlabs) was placed before the samples to generate the circularly polarized excitation. All data is processed using origin drawing.

Metal-halide perovskites possess excellent optical gain, narrow emission linewidths, and high emission efficiency, rendering them highly promising for next-generation laser applications. Thermal evaporation, a mature semiconductor fabrication technique, offers a viable route toward scalable production. However, to monitor the phase distribution of perovskites in thermally evaporated process is still challenging. Here, we systematically investigated and regulated thermally evaporated FAXCs0.8PbBr3 perovskite films by tuning the FA content to optimize the phase distribution. At an intermediate FA content, the film exhibited a more balanced distribution of n = 2 to n = 5 quantum-well phases, which facilitated ultrafast carrier transfer (<0.31 ps) and suppressed nonradiative recombination. FA+ actively participates in the perovskite lattice as an A-site cation, contributing to more ordered crystallization and lower defect densities. The optimized film achieved a net modal gain of 1041 cm-1 and a gain lifetime as long as 129 ps. Furthermore, benefiting from the efficient internal scattering, the threshold for cavity-free random lasing is successfully effectively reduced to below 5 μJ/cm² at room temperature. The low spatial coherence of the random lasing enabled speckle-free imaging with a speckle contrast as low as 0.011 and improved contrast-to-noise ratios across all spatial frequencies. This work provides a scalable strategy for perovskite composition-phase engineering, paving the way toward speckle-free laser imaging systems compatible with semiconductor-grade, large-area manufacturing techniques.