Automated Author Profile

Jiri Brabec

Current S-Index

1.3

Sum of Dataset Indices for all datasets

Average Dataset Index per Dataset

0.7

Average Dataset Index per dataset

Total Datasets

2

Total datasets for this author

Average FAIR Score

13.5%

Average FAIR Score per dataset

Total Citations

2

Total citations to the author's datasets

Total Mentions

0

Total mentions of the author's datasets

S-Index Interpretation

S-Index Over Time

Cumulative Citations Over Time

Cumulative Mentions Over Time

Datasets

A MRCC study of the isomerisation of cyclopropane

Mukherjee's and Brillouin-Wigner multi-reference coupled cluster methods with universal state selective (USS) corrections were used to study the isomerisation of cyclopropane to propene through a trimethylene/propylidene diradicals. Main aim was to obtain high quality ab-initio data using advanced methods that treat both static and dynamic correlation in the involved species, however, we also report implementation of the diagonal USS correction in the LPNO-MRCC code and its performance assessment. The MkCCSD(T)/cc-pV5Z lower bound of interaction energy of cyclopropane isomerisation via trimethylene is 65.6 kcal/mol (59.9 kcal/mol with ZPVE correction), in a good agreement with experimental values in the range 60–65 kcal/mol. The MkCCSD(T)/cc-pV5Z adiabatic singlet-triplet gap in trimethylene is 0.6 kcal/mol, slightly higher than previous CASPT2 result −0.7 kcal/mol by Skancke et al.

Authors

  • Lang, Jakub ;
  • Švaňa, Matej ;
  • Ondřej Demel ;
  • Jiri Brabec ;
  • Kedžuch, Stanislav ;
  • Noga, Jozef ;
  • Kowalski, Karol ;
  • Jiří Pittner
1 Citation0 Mentions13% FAIR0.7 Dataset Index
10.6084/m9.figshare.4985177January 2017

A MRCC study of the isomerisation of cyclopropane

Mukherjee's and Brillouin-Wigner multi-reference coupled cluster methods with universal state selective (USS) corrections were used to study the isomerisation of cyclopropane to propene through a trimethylene/propylidene diradicals. Main aim was to obtain high quality ab-initio data using advanced methods that treat both static and dynamic correlation in the involved species, however, we also report implementation of the diagonal USS correction in the LPNO-MRCC code and its performance assessment. The MkCCSD(T)/cc-pV5Z lower bound of interaction energy of cyclopropane isomerisation via trimethylene is 65.6 kcal/mol (59.9 kcal/mol with ZPVE correction), in a good agreement with experimental values in the range 60–65 kcal/mol. The MkCCSD(T)/cc-pV5Z adiabatic singlet-triplet gap in trimethylene is 0.6 kcal/mol, slightly higher than previous CASPT2 result −0.7 kcal/mol by Skancke et al.

Authors

  • Lang, Jakub ;
  • Švaňa, Matej ;
  • Ondřej Demel ;
  • Jiri Brabec ;
  • Kedžuch, Stanislav ;
  • Noga, Jozef ;
  • Kowalski, Karol ;
  • Jiří Pittner
1 Citation0 Mentions13% FAIR0.7 Dataset Index
10.6084/m9.figshare.4985177.v1January 2017