Materials Data on ZnPdF6 by Materials Project

PdZnF6 crystallizes in the trigonal R-3 space group. The structure is three-dimensional. Pd4+ is bonded to six equivalent F1- atoms to form PdF6 octahedra that share corners with six equivalent ZnF6 octahedra. The corner-sharing octahedral tilt angles are 42°. All Pd–F bond lengths are 1.96 Å. Zn2+ is bonded to six equivalent F1- atoms to form ZnF6 octahedra that share corners with six equivalent PdF6 octahedra. The corner-sharing octahedral tilt angles are 42°. All Zn–F bond lengths are 2.05 Å. F1- is bonded in a bent 150 degrees geometry to one Pd4+ and one Zn2+ atom.