Materials Data on Ti3Rh5 by Materials Project

Ti3Rh5 crystallizes in the orthorhombic Pbam space group. The structure is three-dimensional. there are two inequivalent Ti sites. In the first Ti site, Ti is bonded in a body-centered cubic geometry to eight Rh atoms. There are a spread of Ti–Rh bond distances ranging from 2.55–2.71 Å. In the second Ti site, Ti is bonded in a 10-coordinate geometry to ten Rh atoms. There are a spread of Ti–Rh bond distances ranging from 2.60–2.88 Å. There are three inequivalent Rh sites. In the first Rh site, Rh is bonded in a 6-coordinate geometry to six Ti atoms. In the second Rh site, Rh is bonded in a 5-coordinate geometry to five Ti atoms. In the third Rh site, Rh is bonded in a 6-coordinate geometry to six Ti atoms.