Materials Data on CoAg(N3O4)2 by Materials Project

CoAg(NO2)4N2 crystallizes in the tetragonal P4/nnc space group. The structure is zero-dimensional and consists of four ammonia molecules, two cobalt molecules, and two Ag(NO2)4 clusters. In each Ag(NO2)4 cluster, Ag1+ is bonded in a 8-coordinate geometry to eight equivalent O2- atoms. All Ag–O bond lengths are 2.54 Å. N2+ is bonded in a bent 120 degrees geometry to two equivalent O2- atoms. Both N–O bond lengths are 1.24 Å. O2- is bonded in a distorted single-bond geometry to one Ag1+ and one N2+ atom.