Materials Data on TbCrTeO6 by Materials Project

TbCrTeO6 is beta Vanadium nitride-derived structured and crystallizes in the trigonal P-31c space group. The structure is three-dimensional. Tb3+ is bonded to six equivalent O2- atoms to form TbO6 octahedra that share corners with six equivalent CrO6 octahedra and edges with three equivalent TeO6 octahedra. The corner-sharing octahedral tilt angles are 60°. All Tb–O bond lengths are 2.28 Å. Cr5+ is bonded to six equivalent O2- atoms to form CrO6 octahedra that share corners with six equivalent TbO6 octahedra and corners with six equivalent TeO6 octahedra. The corner-sharing octahedra tilt angles range from 42–60°. All Cr–O bond lengths are 2.10 Å. Te4+ is bonded to six equivalent O2- atoms to form TeO6 octahedra that share corners with six equivalent CrO6 octahedra and edges with three equivalent TbO6 octahedra. The corner-sharing octahedral tilt angles are 42°. All Te–O bond lengths are 1.97 Å. O2- is bonded in a distorted trigonal planar geometry to one Tb3+, one Cr5+, and one Te4+ atom.